Preparation and Properties of Transparent SEBS/Titania Nanocomposite Films via Functionalization of SEBS and Sol–Gel Process

Author:

Guo Huanwang1,Li Xue1

Affiliation:

1. Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, 106 Jiwei Road, Jinan 250022, People's Republic of China

Abstract

Transparent nanocomposite films based on a thermoplastic elastomer, poly[styrene- b-(ethylene- co-butylene)- b-styrene] triblock copolymer (SEBS), and titania sol-gel precursors are fabricated. The SEBS grafted with maleic anhydride (SEBS-g-MAH) can enhance the dispersion of titania in the SEBS matrix. The SEBS- g-MAH/titania nanocomposite films are transparent and exhibit excellent mechanical properties, including increased modulus and tensile strength, with only a slight loss of stretchability. Moreover, the uniformly dispersed titania nanoparticles in the SEBS-g-MAH matrix can enhance thermal stability of the nanocomposites.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,Ceramics and Composites

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