Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto Fe3O4@Mg2Al-NO3 Layered Double Hydroxide in aqueous solution

Abstract

The adsorption of Pb(II) and Cu(II) onto Fe3O4@Mg2Al-NO3 Layered Double Hydroxide (LDH) as a function of Fe3O4@Mg2Al-NO3 LDH concentration was studied. An adsorbent concentration effect ( Cs effect), namely adsorption isotherm declines as adsorbent concentration ( Cs) increases, was observed. The experimental data were fitted to the adsorption models including the classic Freundlich model, the metastable-equilibrium adsorption theory, the flocculation model, the power function model, and the surface component activity model. The results show that the Freundlich-type metastable-equilibrium adsorption equation, the power function model, and the Freundlich-surface component activity equation can adequately describe the Cs effect observed in the batch adsorption tests as all the correlation coefficients ( R2) of the nonlinear plots are higher than 0.96. In other words, their intrinsic parameters simulated from the experimental data are independent of Cs value. It is considered that the Freundlich-surface component activity equation is the best model to describe the Cs effect of the studied adsorption systems by Akaike Information Criterion evaluation criterion.