Solubility of Blowing Agents HCFC 142b, HFC 134a, HFC 125 and Isopropanol in Polystyrene

Author:

Daigneault Louis E.1,Handa Y. Paul1,Wong Betty1,Caron Louis M.2

Affiliation:

1. National Research Council of Canada, Industrial Materials Institute, 75 de Mortagne Blvd., Boucherville, Québec J4B 6Y4, Canada

2. OC Celfortec Inc.

Abstract

The vapor-liquid equilibria of HCFC 142b, HFC 134a, HFC 125 and isopropanol in polystyrene were determined in a closed high pressure vessel at temperatures up to 220°C. Complete solubility maps are presented for each blowing agent, including conditions for phase separation in the polystyrene phase. In order of decreasing solubility, the blowing agents rank isopropanol > HCFC 142b > HFC 134a > HFC 125. In the cases of isopropanol and HFC 134a, some solubility results obtained by the vapor pressure method and those using a high-pressure electrobalance are compared.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,General Chemistry

Reference8 articles.

1. Physical Properties of Blowing Agent Polymer Systems—I. Solubility of Fluorocarbon Blowing Agents in Thermoplastic Resins

2. 3. B. Wong and Y. P. Handa, A High-Pressure Electro balance Based in-situ Technique for Determining the Solubility and Diffusivity of Gases in Polymers, ANTEC 97, 1979 (1997).

3. Compressibility factors and virial coefficients of 2-propanol

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