Vacuum Pyrolysis of Brazilian coal, peat and biomass – Results on characterization of feedstock, solid residues, pyrolysis liquids and conversion rates

Abstract

Pyrolysis of solid fuels such as coal, peat and biomass enables conversion into solid and liquid products, with noncondensable gas being a by-product. The present study evaluates conversion characteristics of Brazilian coal, peat and biomass samples using vacuum pyrolysis techniques. Feedstock and their respective solid residues (chars) and pyrolytic liquids obtained under vacuum pyrolysis conditions were characterized by proximate and ultimate analyses, gross calorific value, petrographic analyses, reactivity to CO2, Raman spectroscopy and organic geochemical methods (extraction, liquid chromatography). Chemical and physical properties in the feedstock samples and solid residues are highly variable. In the coals mean vitrinite reflectances ranged from 0.44% to 1.18% Rrandom indicating a rank range from subbituminous to high volatile/medium volatile bituminous coal. Reflectance measurements obtained from vitrinoid particles identified in solid residues from coal, peat and biomass varied from 2.10% to 10.64% Rrandom. Analyses of the liquid products indicate a tendency of the aliphatic fraction to increase in most of the samples during the pyrolysis process, as well as the predominant formation of polar compounds in the condensable liquids. The results of this study suggest that among the coal samples investigated major conversion to liquids and gases (29.7%–33.2%) occurs in the high volatile bituminous coals from Santa Catarina, whereas in the biomass samples Mamona (Castor Beans), wood chips (Eucalyptus), wooden bars (pinus) and signal grass have all conversion rates > 60%. The conversion rates for the peat samples varied between 32.5 and 46.6%. Reflectance values determined on vitrinoid biomass chars indicate a potential use in soil amendment.