In this work, we present a new classification of nilpotent orbits in a real reductive Lie algebra
g
{\mathfrak {g}}
under the action of its adjoint group. Our classification generalizes the Bala-Carter classification of the nilpotent orbits of complex semisimple Lie algebras. Our theory takes full advantage of the work of Kostant and Rallis on
p
C
{\mathfrak {p}}_{{}_{\mathbb {C}}}
, the “complex symmetric space associated with
g
{\mathfrak {g}}
”. The Kostant-Sekiguchi correspondence, a bijection between nilpotent orbits in
g
{\mathfrak {g}}
and nilpotent orbits in
p
C
{\mathfrak {p}}_{{}_{\mathbb {C}}}
, is also used. We identify a fundamental set of noticed nilpotents in
p
C
{\mathfrak {p}}_{{}_{\mathbb {C}}}
and show that they allow us to recover all other nilpotents. Finally, we study the behaviour of a principal orbit, that is an orbit of maximal dimension, under our classification. This is not done in the other classification schemes currently available in the literature.