This work addresses the questions: (i) Among all left-invariant Riemannian metrics on a given Lie group, is there any whose isometry group or isometry algebra contains that of all others? (ii) Do expanding left-invariant Ricci solitons exhibit such maximal symmetry? Question (i) is addressed both for semisimple and for solvable Lie groups. Building on previous work of the authors on Einstein metrics, a complete answer is given to (ii): expanding homogeneous Ricci solitons have maximal isometry algebras although not always maximal isometry groups.
As a consequence of the tools developed to address these questions, partial results of Böhm, Lafuente, and Lauret are extended to show that left-invariant Ricci solitons on solvable Lie groups are unique up to scaling and isometry.