Evaluation of pesticide residues in vegetables from Mekong, Delta, Vietnam using LC-MS/MS

Abstract

Purpose: To assess the levels of pesticide residues in commonly used vegetables in Vietnam as a reference for future monitoring. Methods: A total of 180 samples of six different fresh vegetables including watercress, mustard green, choy sum, daikon, okra, and yam were analyzed from Mekong Delta, Vietnam. Ten popular pesticides were evaluated using liquid chromatography-tandem mass spectrometry (LC-MS/MS) after extraction with a multi-residue method (QuEChERS method). Results: The results were assessed according to the maximum residue limit (MRL) provided by Codex for each pesticide in each commodity. Pesticide residues above the MRL were detected in 107 samples (59 %) and 63 samples (47 %) contained residues below the MRL. Multiple residues were present in 38.3% of the samples with two to five pesticides, and 0.6 % of samples were contaminated with more than five pesticide residues. Of the pesticides investigated, eight pesticides were detected, of which abamectin, alpha-cypermethrin, acetamiprid, chlorpyrifos- ethyl, chlorantraniliprole, fenobucarb, fipronil, and trichlorfon exceeded their MRLs. Pesticide residues were detected above MRLs in samples of watercress (14 samples), mustard green (24 samples), choy sum (25 samples), daikon (26 samples), and yam (18 samples). Chlorpyrifos-ethyl, and fipronil were detected in most of the vegetable samples (100% and 89.44%, respectively). Conclusion: The results indicate the occurrence of pesticide residues in commonly consumed vegetables in Vietnam. The need for the regular monitoring of pesticide residues and the sensitization of farmers to better pesticide safety practices, especially the need to adhere to recommended pre-harvest intervals is recommended.