1. 14) The numbering of carbons in glycoside moiety is described in Scheme 1. Glc2-Bu (3a):1H NMR δH(CD3OD): 0.83 (3H, t,J=7.4 Hz, CH3), 1.31 (2H, m, CH2CH3), 1.50 (2H, m, CH2CH2CH3), 3.16–3.81 (14H, OCH2, and protons on the carbons of the maltose), 4.16 (1H, d,J=8.1 Hz, 1-H), 5.08 (1H, d,J=3.9 Hz, 1′-H). ESI-MS [M + NH4]+m⁄z416.3. Calcd. for [M + NH4]+, 416.2. Glc3-Bu(4):1H NMR δH(CD3OD): 0.93 (3H, t,J=7.6 Hz, CH3), 1.40 (2H, m, CH2CH3), 1.59 (2H, m, CH2CH2CH3), 3.22–3.39 (20H, OCH2, and protons on the sugar carbons), 4.28 (1H, d,J=7.8, 1-H), 5.13 (1H, d,J=3.8 Hz, 1′-H), 5.16 (1H, d,J=3.8 Hz, 1″-H). ESI-MS [M + NH4]+m⁄z578.2. Calcd. for [M + NH4]+, 578.3. Glc4-Bu (5):1H NMR δH(CD3OD): 0.92 (3H, t,J=7.6 Hz, CH3), 1.40 (2H, m, CH2CH3), 1.60 (2H, m, CH2CH2CH3), 3.25–3.89 (26H, OCH2, and protons on the sugar carbons), 4.30 (1H, d,J=7.8 Hz, 1-H), 5.14 (1H, d,J=3.8 Hz, 1′-H), 5.17 (1H, d,J=3.8 Hz, 1″-H), 5.19 (1H, d,J=3.8 Hz, 1''″-H). ESI-MS [M + NH4]+m⁄z740.4. Calcd. for [M + NH4]+, 740.3. Glc2-Oc (3b):1H NMR δH(CD3OD): 0.81 (3H, t,J=6.6 Hz, CH3), 1.21 (8H, m, 4×CH2), 1.53 (4H, m, 2×CH2), 3.05–3.86 (15H, OCH2, and protons on the sugar carbons), 3.94 (1H, d,J=7.8 Hz, 1-H), 5.04 (1H, d,J=3.7 Hz, 1′-H). ESI-MS [M + NH4]+m⁄z472.2. Calcd. for [M + NH4]+, 472.2. Glc3-Oc (6):1H NMR δH(CD3OD): 0.81 (3H, t,J=6.9 Hz, CH3), 1.20 (8H, m, 4×CH2), 1.52 (4H, m, 2×CH2), 3.10–3.64 (20H, OCH2, and protons on the sugar carbons), 4.18 (1H, d, 1-H), 5.10 (1H, d,J=3.7 Hz, 1′-H), 5.12 (1H, d,J=3.7 Hz, 1″-H). ESI-MS [M + NH4]+m⁄z634.2. Calcd. for [M + NH4]+, 634.3. Glc4-Oc (7):1H NMR δH(CD3OD): 0.91 (3H, t,J=6.9 Hz, CH3), 1.29 (6H, m, 3×CH2), 1.38 (2H, m, CH2CH3), 1.61 (4H, m, 2×CH2), 3.17–4.00 (26H, OCH2, and protons on the sugar carbons), 4.32 (1H, d,J=7.8 Hz, 1-H), 5.05 (1H, d,J=3.9 Hz, 1′-H), 5.07 (1H, d,J=3.9 Hz, 1″-H) 5.10 (1H, d,J=3.9 Hz, 1''″-H). ESI-MS (M + NH4)+m⁄z796.4. Calcd. for [M + NH4]+, 796.4. Glc2-La (3c):1H NMR δH(CD3OD): 0.89 (3H, t,J=6.6 Hz, CH3), 1.29 (14H, m, 7×CH2), 1.35 (2H, m, CH2CH3), 1.61 [4H, m, OCH2(CH2)2], 3.19–. (Remark: This note is truncated in the html because it exceeds the limit of the system (4000 characters per note). The complete text is given in the pdf.)