1. b[1.8 x 109/()0.5J [T(K)/llll _ 0.5J TO.5pO.2e-13,700/RT 34 (2) 5.52 x 108 T1.0 p-O.825 e-24,400/RT 37 (3) 6.9 x 109 T1•Op-O.825 Ae-EQR/RT36
2. 38-40 -=== 1t11lidl.'-f.rAt.l.mIr; Purchased from American Institute ofAeronautics and Astronautics
3. to describe the initial fuel disappearance. The model also significantly modified and extended the set of elementary reactions included by Edelman and Fortune34and added a number of intermediate (nonelementary) reactions of species such as HCO, H2CO, CH3, C2H4, C2H2, etc. (The complete mechanism appears in Ref. 46.) It is unclear in these publications how the rate expressions for reactions (5c-5e) were derived. However, it appears that the reaction orders in the associated rate correlations are equal to the stoichiometric coefficients of reactions (5c-5e) and the rate constants themselves were obtaied b matching the first correlation appearing in Table 3. 2,45- 47 the mechanism derived in this .IIdI'J'- Purchased from American Institute ofAeronautics and Astronautics
4. b -=.E.!./R. o 543 o 25,000 -1 2,000 o 24,700 o 2,590 o 393 o 4,750 o 8,450 o 0 ° 0 ° 0 o 0 o 37,750 -1.0 60,600 -2.5 64,600 o 44,300 1.0 19,450 -0.5 74,900 o 33,000 -1.5 52,600 o 22,900 o 0 ° 0 -1/2 4,000 -1/2 2,500 1t11lidl.'-f.rAt.l.mIr; Purchased from American Institute ofAeronautics and Astronautics