Electrodeposition of lanthanides from ionic liquids and deep eutectic solvents

Abstract

Lanthanides belong to the most important raw materials and are highly demanded in high-tech industry. Low-temperature electrochemical deposition of lanthanides and lanthanide-based alloys for recycling and obtaining functional materials can provide a real alternative to the currently used high-temperature electrolysis of molten salts. The review summarizes the advancements in the field of electrodeposition of lanthanides from organic ionic systems, such as ionic liquids and deep eutectic solvents. The growing interest in these ionic systems is due to their excellent physicochemical properties, in particular non-volatility, thermal and electrochemical stability. The review also discusses further prospects and potential of the electrochemical approach for obtaining lanthanide-containing advanced materials. The bibliography includes 219 references.