Stability of polymer jets in extension: physicochemical and rheological mechanisms

Abstract

The review is devoted to the fundamental problems of physical chemistry and rheology posed in the analysis of stability loss of polymer jets in extension. Studies of phenomena occurring in deformation of polymeric fluids are of considerable applied interest because extension of polymeric fluids underlies many industrial processes, first of all, fibre spinning. Studies of critical conditions of deformation are based on general principles of fluid mechanics, which are applicable to all fluids and various phenomena in nature and technology. First we discuss solutions to classical problems of instability of liquid jets as the basis for further analysis of the behaviour of polymeric fluids in particular situations. Next, specific features of the deformation mechanisms and appearance of instabilities of polymeric fluid jets are considered as consequences of their physicochemical and rheological properties. The bibliography includes 162 references.