CHLOROPRENE RUBBER: APPLICATION AND PRODUCTION

Author:

Treger Yu. A.1,Morozov K. A.2,Dasaeva G. S.1,Frolkova A. K.3

Affiliation:

1. Scientific Research Engineering Center "Sintez"

2. Scientific Research Engineering Center "Sintez"; MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)

3. MIREA - Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)

Abstract

Polychloroprene is widely used as a special-purpose rubber in such industries as automotive, construction, textile industry. Chloroprene rubber takes a significant share in the market of elastomers due to its properties. In recent years, a gradual increase in demand for chloroprene rubbers is expected. This trend is most clearly seen in regions with a developed automotive industry. World leaders in the production of chloroprene rubbers and latex demonstrate their interest in increasing production capacity. In Russia, chloroprene rubber is not produced, the demand is completely met by import. In this paper, the main industrial methods for the production of chloroprene monomer, based on various feedstocks: acetylene and butadiene-1,3, exist in the world practice. Advantages and disadvantages of each of the above methods for producing chloroprene monomer are given. Technical solutions for the improvement of the chloroprene-monomer preparation technology for the steps of chlorination of butadiene-1,3 and dehydrochlorination of 3,4-dichlorobutene-1 in a column apparatus are proposed. An improved process for the preparation of chloroprene rubber from butadiene-1,3 is described. The development of a modern technology for the production of chloroprene rubber based on domestic raw materials will make it possible to obtain a high-quality target product, which will lead to the exclusion of its imports.

Publisher

RTU MIREA

Reference23 articles.

1. Bauchwitz P.S., Finlay J.B., Stewart C.А. Chloroprene / In: Vinyl and Diene Monomers / E.C. Leonard Jr., ed. Part II. John Wiley & Sons, Inc., 1971. Р. 1149–1183.

2. Carothers W.H., Collins A.M. Halogen derivative of acetylene polymers and the method of their production: pat. 1,950,431 United States. No. 490,538; filled 10/22/1930; publ. 03/13/1934.

3. Oshanina I.V., Bruk L.G., Temkin O.N. Alternative methods for obtaining products of basic organic synthesis. Moscow: MITHT, 2002. 106 p. (in Russ.)

4. Richards J.H., Stewart C.A. Chlorination process: pat. 1435826 GB. No. 46223/73; filled 03/10/1973; publ. 05/19/1976.

5. Itsuo Tabata, Selichi Watanabe, Masayuki Shinoyama. Process for producing dichlorobutene: pat. 2051059 GB. No. 8016493; filled 05/19/1980; publ. 01/14/1981.

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3