Behavior of morpholine and its trimethylsilyl derivative in reactions with trimethylsilyl isocyanate-Reference-Cited by-同舟云学术

Behavior of morpholine and its trimethylsilyl derivative in reactions with trimethylsilyl isocyanate

Published:2022-11-19 Issue:5 Volume:17 Page:377-383
ISSN:2686-7575
Container-title:Fine Chemical Technologies
language:
Short-container-title:Fine Chem. Technol.

Author:

Belova L. O.¹^ORCID,Golub N. A.¹^ORCID,Pletneva M. V.¹^ORCID,Kirilina N. I.²^ORCID,Kirilin A. D.¹^ORCID

Affiliation:

1. MIREA – Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)

2. State Research Institute of Chemistry and Technology of Organoelement Compounds

Abstract

Objectives. To study the patterns of behavior of morpholine and its trimethylsilyl derivative in reactions with trimethylsilyl isocyanate.Methods. The study employed infrared and nuclear magnetic resonance spectroscopy, as well as elemental analysis.Results. The formation of mixtures of tautomeric forms of silicon-containing urea—N-(trimethylsilyl) morpholine-4-carboxamide and trimethylsilylmorpholine-4-carboximidoate—was established.Conclusions. It is shown that the composition and structure of the resulting products are determined both by the presence of a morpholine substituent at the nitrogen atom and by the type of isocyanate used. Unlike the trimethylsilyl derivative of morpholine, morpholine itself reacts with trimethylsilyl isocyanate to form a mixture of tautomeric forms.

Publisher

RTU MIREA

Subject

Inorganic Chemistry,Organic Chemistry,Fluid Flow and Transfer Processes,Process Chemistry and Technology

Reference12 articles.

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