Development of Nitrocellulose-based Propellants With Natural Stabilizers

Author:

Leonard Barboza Rodrigues Rodrigo1ORCID,Ferrapontoff Lemos Maurício2ORCID,Celmar Costa França Tanos1ORCID,Gonçalvez Mendonça Filho Letivan1ORCID

Affiliation:

1. Instituto Militar de Engenharia – Departamento de Engenharia Quimica – Rio de Janeiro/RJ – Brazil

2. Instituto de Pesquisa da Marinha – Grupo de tecnologia de Materiais – Rio de Janeiro/RJ – Brazil

Abstract

Traditional stabilizers for nitrocellulose-based (NC-based) propellants are known to have carcinogenic, mutagenic and toxicity to reproduction potentials. Therefore, the replacement of these stabilizers in the propellants formulations is necessary, but with no losses regarding stabilization efficiency and shelf life of propellant. In this context, NC-based propellants were prepared using the natural substances curcumin and guaiacol as stabilizers. The chemical stability of the samples evaluated by a heat-flux microcalorimeter (HFC) suggests that the new propellants are more stable than the traditional ones. Also, a complementary in silico analysis was performed on toxicity prediction software (LAZAR, Toxtree, VEGA and TEST) based on the similarity with substances contained in their databases. The results concluded that curcumin stabilizer presents no toxicity, while guaiacol can have carcinogenic and mutagenic potential.

Publisher

FapUNIFESP (SciELO)

Subject

Aerospace Engineering

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4. requirements using heat flow calorimetry. Brussels (Belgium): NATO.

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