AN EXTERNAL BEAM TECHNIQUE OF PIXE FOR URANIUM DETERMINATION IN ENVIRONMENTAL OBJECTS

Author:

Kuzmenko V.V.,Levenets V.V.,Omelnik O.P.,Rolik I.L.,Shchur A.O.

Abstract

The possibilities of the determination of the content of uranium in materials of the nuclear fuel cycle and environmental objects using the nuclear-physical methods of analysis based on registration of characteristic X-rays excited by protons (PIXE) are considered. It is shown that the introduction to X-ray emission spectrometer the element with a wave dispersion – a pyrocarbon filter, using Bragg-Wulf reflection from the planes of the crystal lattice, makes it possible to reduce the detection limit of uranium in the presence of interfering impurities to a value of 0.0005 mas.%. The proposed approach can be used to determine Th, Pu, and other actinides.

Publisher

Problems of Atomic Science and Technology

Reference4 articles.

1. S.A.E. Johansson, T.B. Johansson. Analytical application of particle induced X-ray emission // Nucl. Instr. Meth. 1976, v. 137, p. 473-516.

2. V.N. Bondarenko, L.S. Glasunov, A.V. Goncha-rov, A.V. Zats, V.V. Kuzmenko, V.V. Levenets, A.P. Omelnik, V.M. Pistryak, V.I. Sukhostavets, A.A. Shchur, N.P. Usikov. NSC KIPT analytical nuclear-physical complex “SOKOL” // International Conference Current Problems of Nuclear Physics and Atomic Energy (NPAE-Kyiv 2006), May 29–June 03, 2006, Kyiv, Ukraine, p. 163.

3. V.V. Levenets, O.P. Omelnyk, A.O. Shchur, E.A. Chernov. The using of PIXE and pyrolytic graphite filter to determine of Fe in ZrF4 // The Journal of Kharkiv National University physical. Series “Nuclei, Particles, Fields”. 2007, N 2(34), p. 84-88.

4. O.P. Omelnyk, V.V. Levenets, A.Yu. Lonin, I.V. Shevchenko, A.O. Shchur. Determination of the Content of Hf in Zirconium Alloys with using a Wide Band X-Ray Emission Filter // Methods and objects of chemical analysis. 2018, v. 13, N 4, p. 153-159.

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