Affiliation:
1. Institut de Physique, Université de Fribourg, Pérolles, CH-1700 Fribourg, Switzerland
Abstract
Yttrium, lantanum and rare earth elements can be loaded with hydrogen inducing a metal–insulator transition and giving rise to optical switching from reflecting to transparent. We present angle-scanned photoemission experiments characterizing thin YbH x films grown on W(110) at room temperature. Hydrogen loading is performed in an ultrahigh-vacuum-compatible high pressure (1 bar) reaction cell. Via full-hemispherical X-ray photoelectron diffraction and low energy electron diffraction, it is demonstrated that these films grow well-ordered and single-crystalline. Ultraviolet photoemission reveals a gap for the dihydride phase confirming a transition from reflecting to transparent as seen by visual inspection. Ion implantation through additional H+ sputtering allows one to increase the hydrogen content to x ≈ 2.4.
Publisher
World Scientific Pub Co Pte Lt
Subject
Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics
Cited by
3 articles.
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