X-RAY ABSORPTION EVIDENCE FOR THE BACK-DONATION IN IRON CYANIDE COMPLEXES-Reference-Cited by-同舟云学术

X-RAY ABSORPTION EVIDENCE FOR THE BACK-DONATION IN IRON CYANIDE COMPLEXES

Published:2002-02 Issue:01 Volume:09 Page:359-364
ISSN:0218-625X
Container-title:Surface Review and Letters
language:en
Short-container-title:Surf. Rev. Lett.

Author:

VINOGRADOV A. S.¹,PREOBRAJENSKI A. B.²,KRASNIKOV S. A.²,CHASSÉ T.²,SZARGAN R.²,KNOP-GERICKE A.³,SCHLÖGL R.³,BRESSLER P.⁴

Affiliation:

1. Institute of Physics, St. Petersburg State University, St. Petersburg, 198504, Russia

2. W.-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, Leipzig, D-04103, Germany

3. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, Berlin, D-14195, Germany

4. BESSY GmbH, Albert-Einstein-Str. 15, Berlin, D-12489, Germany

Abstract

High-resolution, uniformly calibrated Fe 2p 3/2 absorption spectra of various Fe(II) and Fe(III) compounds with the metal atom octahedrally coordinated to atomic and molecular ligands are analyzed expecting changes in the absorption spectra due to differences in the formal valence state and in the character of the chemical bond. Particular attention is given to revealing spectral characteristics of the 3d π–2π(π*) charge transfer (π-back-donation effect) between the iron atom and cyanide ligands.

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

Link

https://www.worldscientific.com/doi/pdf/10.1142/S0218625X02002270

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