INVESTIGATION OF POROUS ANODIC FILM FORMATION ON AA1050 BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY

Author:

DANIŞMAN M.1,KOCABAŞ M.2,CURIONI M.3,CANSEVER N.4

Affiliation:

1. Faculty of Engineering, Electrical and Electronics Engineering Department, Istanbul Gedik University, Yakacik 34876, Istanbul, Turkey

2. Faculty of Engineering and Natural Sciences, Department of Metallurgical and Materials Engineering, Konya Technical University, 42075 Konya, Turkey

3. School of Materials, Corrosion and Protection Centre, University of Manchester, M139PL Manchester, UK

4. Faculty of Chemistry-Metallurgy, Metallurgical and Materials Engineering Department, Yildiz Technical University, 34210 Istanbul, Turkey

Abstract

In this study, the formation of porous Al2O3 on commercial 1050 aluminium alloy (AA1050) in 2[Formula: see text]M sulfuric acid (H2SO4) electrolyte was investigated. Anodization was performed at 12[Formula: see text]V and 15[Formula: see text]V specimens for a charge density of 757[Formula: see text]mC/cm2 and 3231[Formula: see text]mC/cm2. The resulting oxides were analyzed using scanning electron microscopy (SEM). According to analysis, a hexagonal oxide formation containing more than one nano pore was observed on the surface of the specimen. The structural properties of the porous oxide film were analyzed with electrochemical impedance spectroscopy (EIS) analysis and film-related features such as thickness of the porous and the barrier layer were obtained.

Funder

EPSRC

The Scientific and Technological Research Council of Turkey

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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