EFFECTS OF PRECURSOR SOLUTION MODIFICATION ON THE CRYSTALLINITY AND ELECTRICAL PROPERTIES OF Na0.5Bi0.5TiO3-BiFeO3 BASED THIN FILM

Abstract

For chemical solution decomposition process, the precursor solution is a basic factor affecting the quality of the deposited-film. In this paper, we choose (l00)-oriented 0.7[( Bi 0.95 Ce 0.05)0.5 Na 0.5( Ti 0.99 Fe 0.01) O 3]-0.3 BiFe 0.97 Mn 0.03 O 3(0.7 NBTCeFe -0.3 BFOMn ) thin films prepared by various precursor solutions for investigation. The roles of precursor solution modification on crystallinity, ferroelectric and dielectric properties are characterized. With the addition of polyethylene glycol into the solution, phase-pure perovskite structure can be obtained. Furthermore, when the volume ratio for the solvents (ethylene glycol to acetic acid) is modified as 2:1, enhanced ferroelectricity can be achieved with a remanent polarization (Pr) of 27.5 μC/cm2, which coincides well with the capacitance–voltage curve with relatively sharp feature. Also, the 0.7 NBTCeFe -0.3 BFOMn film exhibits a dielectric constant (εr) of 576 and dielectric loss (tan δ) of 0.123 at 100 kHz.