LEED AND STM STUDY OF Cs ON Cu(211)

Author:

CARAGIU M.1,SEYLLER TL.1,DIEHL R. D.1,NORRIS A. G.2,McGRATH R.2,MURYN C. A.3

Affiliation:

1. Physics Department, Penn State University, University Park, PA 16802, USA

2. Surface Science Centre, University of Liverpool, Liverpool, L69 3BX, UK

3. Chemistry Department, University of Manchester, Manchester, M13 9PL, UK

Abstract

A low-temperature (25 K) STM study of Cs adsorption on Cu(211) indicates that Cs forms variable-density structures which align along the step edges of the Cu(211) surface. The density of the overlayer increases with Cs coverage, forming a quasihexagonal c(2×2) structure at a coverage of 0.17. A dynamical LEED study of that structure at 130 K indicates that the Cs atoms are adsorbed on top of the Cu atoms in the center of the terraces, with a Cs–Cu nearest-neighbor distance of 3.56± 0.04 Å. This structure is accompanied by a significant rumpling of the Cu(211) surface.

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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