PROTON TUNNELING IN THE S1 STATE OF TROPOLONE–M1(M=Ar, Kr, Xe, CH4, CD4, N2) CLUSTERS

Author:

SEKIYA H.1,HAMABE H.1,NAKAJIMA T.1,NISHIMURA Y.1

Affiliation:

1. Institute of Advanced Material Study, and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan

Abstract

The S 1← S 0 fluorescence excitation spectra of jet-cooled tropolone–M1(M= Ar , Kr , Xe , CH 4, CD 4, N 2) clusters have been measured to investigate the effect of intermolecular interactions on proton tunneling. It has been found that the [Formula: see text] tunneling splittings of tropolone–CH4/CD4 and tropolone–N2 are significantly smaller than that of tropolone.

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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