A NOVEL MODEL FOR THE RELATIONSHIP BETWEEN THE HEALING TIME OF THE INERT FILM AND THE INCUBATION PERIOD OF LOCALIZED CORROSION

Author:

ZHAO MINGHAN12ORCID,REN YI2ORCID,CHEN DONGXU1ORCID,WU HAODONG1ORCID,LI JING1ORCID,ZHOU YANWEN1ORCID,WANG XIANG3ORCID

Affiliation:

1. School of Material and Metallurgy, University of Science and Technology Liaoning, Anshan 114051, P. R. China

2. State Key Laboratory of Metal Material for Marine Equipment and Application, Anshan Iron and Steel Research Institute, AnGang Group, Anshan 114000, P. R. China

3. CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, P. R. China

Abstract

A model for the relationship between the healing time of the scratched diamond-like carbon (DLC) film and the localized corrosion incubation period of metal was established. Based on model calculations combined with experimental results, the scratched DLC film on 13Cr stainless steel was able to heal within 10–16[Formula: see text]h in NaCl solution with an adsorbent-type corrosion inhibitor. However, the localized corrosion incubation time was 30–40[Formula: see text]h. Healing of the scratched DLC film can be completed before localized corrosion occurs. This model provides a theoretical reference for the scratch-repassivation of inert films in corrosion inhibitors solutions.

Funder

National Natural Science Foundation of China

National Key Laboratory for Marine Engineering Equipment of Metallic Materials and Application

major R&D project of Liaoning Province, China

Publisher

World Scientific Pub Co Pte Ltd

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