NITRILES ADSORBED ON Si(001) AT 300 K STUDIED VIA SYNCHROTRON RADIATION CORE-ELECTRON SPECTROSCOPIES

Author:

ROCHET FRANÇOIS1,BOURNEL FABRICE1,CARNIATO STEPHANE1,DUFOUR GEORGES1,GALLET JEAN-JACQUES1,ILAKOVAC VITA1,LE GUEN KARINE1,RANGAN SYLVIE1,KUBSKY STEPHAN2,SIROTTI FAUSTO2

Affiliation:

1. Laboratoire de Chimie Physique, Matière et Rayonnement, Université Pierre et Marie Curie, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05, France

2. Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin — BP 48, 91192 Gif sur Yvette Cedex, France

Abstract

This paper focuses on the use and value of XPS and NEXAFS spectroscopies to unveil the nature of the chemical bond of various bifunctional nitrile molecules adsorbed on Si (001) 2×1 at 300 K. The adsorption modes are also discussed in the light of recent theoretical publications devoted to optimized geometries and reaction paths of these molecules on Si (001).

Publisher

World Scientific Pub Co Pte Lt

Subject

Electrical and Electronic Engineering,Computer Science Applications,Condensed Matter Physics,General Materials Science,Bioengineering,Biotechnology

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