The evolution of corrole synthesis — from simple one-pot strategies to sophisticated ABC-corroles

Author:

König Michael1,Faschinger Felix2,Reith Lorenz Michael3,Schöfberger Wolfgang4

Affiliation:

1. Institute of Polymer Chemistry, Johannes Kepler University Linz (JKU), Altenberger Straße 69, A-4040 Linz, Austria

2. Institute of Biophysics, Johannes Kepler University Linz (JKU), Gruberstraße 40, A-4020 Linz, Austria

3. ENGEL AUSTRIA GmbH, Ludwig-Engel-Strasse 1, 4311 Schwertberg, Austria

4. Institute of Organic Chemistry, Johannes Kepler University Linz (JKU), Altenberger Straße 69, A-4040 Linz, Austria

Abstract

This review highlights synthesis procedures to obtain A3-, cis- and trans- A2B- and ABC-corroles. Synthesis methods from the early beginning of “corrole chemistry”, acid-catalyzed condensation methods of various building blocks (pyrrole, aldehyde, dipyrromethane, dipyrromethane-carbinol, and dipyrromethane-dicarbinol etc.), possible side reaction during Brønsted acid catalyzed reactions (scrambling), one-pot synthesis of corroles, and post-macrocyclization modification reactions of meso-substituted A3-corroles are discussed.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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