Synthesis of α,α’-linked penta- and septaheterocycles by tandem Suzuki coupling-Reference-Cited by-同舟云学术

Synthesis of α,α’-linked penta- and septaheterocycles by tandem Suzuki coupling

Published:2019-01 Issue:01n02 Volume:23 Page:28-33
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Zafar Hadiqa¹,Brewster James T.¹,Wight Christopher D.¹,McVeigh Matthew¹,Steinbrück Axel¹,Lynch Vincent M.¹,Sessler Jonathan L.¹²

Affiliation:

1. Department of Chemistry, the University of Texas at Austin, 105 E. 24th St., Stop A5300, Austin, Texas 78712-1224, USA

2. Institute for Supramolecular and Catalytic Chemistry, Shanghai University, Shanghai 200444, China

Abstract

The controlled synthesis of oligoaromatics can provide materials of wide utility. Here, we describe the preparation of higher order oligoheterocycles via a tandem Suzuki cross-coupling protocol. This method has allowed for the iterative construction of fluorescent [Formula: see text],[Formula: see text]-linked penta- and septaheterocyclic systems with modification of the terminal moiety allowing for fine-tuning of the emission features.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424618501080

Reference36 articles.

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