Free-base porphyrin and [60]fullerene linked by oligomeric ethylenedioxythienylenevinylene bridge-Reference-Cited by-同舟云学术

Free-base porphyrin and [60]fullerene linked by oligomeric ethylenedioxythienylenevinylene bridge

Published:2015-01 Issue:01-03 Volume:19 Page:404-410
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Pelado Beatriz¹,Coro Julieta¹²,de la Cruz Pilar¹,Langa Fernando¹

Affiliation:

1. Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), Universidad Castilla-La Mancha, Campus de la Fábrica de Armas, 45072 Toledo, Spain

2. Laboratorio de Síntesis Orgánica, Facultad de Química, Universidad de La Habana, 10400 La Habana, Cuba

Abstract

The synthesis and structural characterization and the study of the electronic properties of two novel porphyrin-bridge-fullerene molecules, where a free-based porphyrin and [60]fullerene are connected through one and two units of ethylenedioxythienylenevinylene π-conjugated bridges, is reported. The absorption studies, voltamperometric measurements and theoretical calculations at DFT level are presented. A HOMO–LUMO gap as low as 1.41 eV has been found for compound 6.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424615500261

Reference8 articles.

1. Electronic Communication through π-Conjugated Wires in Covalently Linked Porphyrin/C60Ensembles

2. Oligothienylenevinylenes as a New Class of Multinanometer Linear π-Conjugated Systems for Micro- and Nanoelectronics

3. Synthesis and Photoinduced Energy‐ and Electron‐Transfer Processes of C 60 –Oligothienylenevinylene–C 70 Dumbbell Compounds

4. Robust Ethylenedioxythiophene-Vinylene Oligomers from Fragile Thiophene-Vinylene Cores: Synthesis and Optical, Chemical and Electrochemical Properties of Multicharged Shapes

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