Electrochemical characterization of β,β′-butanoporphyrins containing sterically hindered meso-2,6-dihalogenophenyl substituents and first-row transition metal ions in nonaqueous media

Abstract

Six [Formula: see text],[Formula: see text]-butano substituted metalloporphyrins containing sterically hindered meso-dihalogenophenyl substituents and first-row transition metal ions were synthesized and their electrochemical and spectroelectrochemical properties were characterized in nonaqueous media. The investigated compounds have the general formula butano(Y2Ph)4PorM, where Por is a dianion of the porphyrin, M = Mn[Formula: see text]Cl, Fe[Formula: see text]Cl, Co[Formula: see text], Ni[Formula: see text], Cu[Formula: see text] or Zn[Formula: see text]and Y2Ph is a sterically hindered 2,6-F2Ph or 2,6-Cl2Ph group on each of the four meso-positions of the macrocycle. The electrochemistry of each porphyrin was examined in CH2Cl2 or pyridine containing 0.1 M tetra-[Formula: see text]-butylammonium perchlorate. The first one-electron reduction is metal-centered for the manganese(III), iron(III) and cobalt(II) porphyrins to generate the Mn(II), Fe(II) and Co(I) porphyrins, but it is porphyrin ring-centered for the other examined M(II) porphyrins to give porphyrin [Formula: see text]-anion radicals under the given solution conditions. The effect of the [Formula: see text],[Formula: see text]-butano and sterically hindered meso-Y2Ph substituents on redox potentials and electron transfer mechanisms are discussed and compared to what was previously reported for butano-substituted tetraarylporphyrins without hindered meso-substituents.