Synthesis and properties of palladium(II) complexes of aromatic hemiporphyrazines-Reference-Cited by-同舟云学术

Synthesis and properties of palladium(II) complexes of aromatic hemiporphyrazines

Published:2014-10 Issue:10n11 Volume:18 Page:869-874
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Muranaka Atsuya¹,Kyotani Fumiko¹,Ouyang Xingmei¹,Hashizume Daisuke²,Uchiyama Masanobu¹³

Affiliation:

1. Elements Chemistry Laboratory, RIKEN and Advanced Elements Chemistry Research Team, RIKEN Center for Sustainable Resource Science (CSRS), Wako-shi, Saitama 351-0198, Japan

2. Materials Characterization Support Unit, RIKEN Center for Emergent Matter Science (CEMS), Wako-shi, Saitama 351-0198, Japan

3. Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

Palladium(II) complexes of aromatic hemiporphyrazines were prepared by the reaction of bis(dibenzylideneacetone)palladium(0) with the corresponding metal-free macrocycles. Single crystal X-ray analysis revealed that a palladium(II) ion was coordinated inside the macrocyclic cavity to form two Pd – C bonds. Electronic properties of the metalloorganic compounds were characterized by NMR, UV-vis-NIR, and magnetic circular dichroism (MCD) spectroscopy.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424614500667

Reference7 articles.

1. [18]/[20]π Hemiporphyrazine: A Redox-Switchable Near-Infrared Dye

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