Metal templated synthesis of a dipyridazinamethyrin and its properties-Reference-Cited by-同舟云学术

Metal templated synthesis of a dipyridazinamethyrin and its properties

Published:2021-10 Issue:10n12 Volume:25 Page:1223-1229
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Xu Kui¹,Ding Wenjing¹,Liu Guopeng¹,Ma Wanzun¹,Yin Yu¹,Chen Xi¹,Wu Lamei¹,Ding Lili²,Zhang Zhan¹^ORCID

Affiliation:

1. Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for Nationalities Wuhan 430074, China

2. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China

Abstract

Presented here is the stepwise and one-pot synthesis of a dipyridazinamethyrin, 1. In either synthetic route, a proper metal cation template was found necessary. 1H NMR and UV-Vis absorption studies suggest this macrocycle exhibits a non-aromatic nature. DFT calculations suggest that the optimized structure of this macrocycle is slightly ruffled rather than planar.

Funder

National Natural Science Foundation of China

Publisher

World Scientific Pub Co Pte Ltd

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424621501236

Reference10 articles.

1. Amethyrin-type expanded porphyrins that display anti-aromatic character upon protonation

2. Synthesis and Antiaromatic Properties of Highly Planar Dithiaamethyrin

3. Synthesis and characterization of an amethyrin-uranyl complex displaying aromatic character

4. Bis[(μ-chloro)copper(II)] Amethyrin: A Bimetallic Copper(II) Complex of an Expanded Porphyrin

5. Aminosilanes in organic synthesis. Preparation of new expanded porphyrin ligands and bimetallic transition-metal complexes. Crystal structure of a tetrapyrrole macrocycle dirhodium complex