Air–water interfacial assembly of all-aromatic-substituted double-decker phthalocyanine forms aligned nanoparticles

Abstract

In this manuscript, unexpected supramolecular assembly of [Formula: see text]-conjugated molecules containing complex aromatic substituents was investigated. The air–water interfacial assembly of double-decker phthalocyanines containing sixteen phenol substituents (Ce(Pc2)[Formula: see text] and Y(Pc2)[Formula: see text] form aligned nanoparticles. Depending on the different surface pressure, the Ce(Pc2)[Formula: see text] self-assembled nanostructures can be regulated thoroughly. Although Ce(Pc2)[Formula: see text] and Y(Pc2)[Formula: see text] have only aromatic substituent groups, no H- or J-aggregation of [Formula: see text]-conjugated systems can be detected from the UV-vis spectra of the assemblies of these double-decker phthalocyanines. When the nanostructures of these assemblies were changed greatly, no corresponding changes of UV-vis spectra and FT-IR spectra could be detected. These unusual results can be understood from the balance between the hydrophilicity of aromatic substituents and the ether linkages of double-decker phthalocyanines and the surface pressure, and open new. approaches for supramolecular assembly of complex [Formula: see text]-conjugated systems.