Ion-pairing assemblies of self-associating pyrrole-based anion-responsive π-electronic molecules
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Published:2022-11-24
Issue:
Volume:
Page:A-I
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ISSN:1088-4246
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Container-title:Journal of Porphyrins and Phthalocyanines
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language:en
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Short-container-title:J. Porphyrins Phthalocyanines
Author:
Haketa Yohei1,
Nishiyama Kenta1,
Maeda Hiromitsu1
Affiliation:
1. Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525–8577, Japan
Abstract
Dipyrrolylbenzenes bearing a tethered carboxylate unit with a countercation have been synthesized as components of anion-binding self-assemblies via hydrogen bonding between the anionic moieties and pyrrole NH units. The 1D-chain self-assembled structures, as negatively charged supramolecular polymers, provide solid-state ion-pairing assemblies, whose assembly modes depend on the coexisting cations.
Funder
JSPS KAKENHI
Scientific Research
Transformative Research Areas (A) “Condensed Conjugation”
Scientific Research on Innovative Areas
Research Center for Computational Science, Okazaki, Japan
BL02B1
BL40XU
Publisher
World Scientific Pub Co Pte Ltd
Subject
General Chemistry