Affiliation:
1. National Research Center for Geoanalysis, China Geological Survey, Beijing 100037, China
2. Beijing Municipal Research Institute of Environmental Protection, Beijing, 100037, China
3. NCS Testing Technology Co., Ltd, Beijing 100081, China
Abstract
Trimerization reaction of 8-(4′-cyanophenyl)-1,3,5,7-tetramethyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (CN-BODIPY) led to the isolation of a new triazine-based BODIPY trimer 2,4,6-tris(8′-phenyl-1′,3′,5′,7′-tetramethyl-4′,4′-difluoro-4′-bora-3a′,4a′-diaza-s-indacene)-1,3,5-triazine (1). This BODIPY trimer 1 have been characterized by a series of spectroscopic methods including MALDI-TOF mass, 1H NMR, electronic absorption, IR and fluorescence spectroscopy. In particular, the single crystals of 1 have be obtained by slow diffusion of methanol into the solution of this compound in CHCl3. The BODIPY trimer structure of 1 with a triazine core has been directly revealed on the basis of single crystal X-ray diffraction analysis with the intermolecular interactions investigated by Hirshfeld surface analysis. This work will be helpful for the design and synthesis of new multiple BODIPY derivatives with various application.
Publisher
World Scientific Pub Co Pte Ltd
Cited by
1 articles.
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