Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety-Reference-Cited by-同舟云学术

Facile synthesis, spectroscopic and electrochemical properties, and theoretical calculations of porphyrin dimers with a bridging amide-bonded xanthene moiety

Published:2015-07 Issue:07 Volume:19 Page:819-829
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Liang Xu¹²,Xu Li¹,Li Minzhi¹,Mack John³,Stone Justin³,Nyokong Tebello³,Jiang Yu¹,Kobayashi Nagao²,Zhu Weihua¹

Affiliation:

1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China

2. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

3. Department of Chemistry, Rhodes University, Grahamstown 6140, South Africa

Abstract

A free base porphyrin dimer bridged by a flexible amide-bonded xanthene moiety and its binuclear zinc(II) complex zinc(II) complex were synthesized and characterized. Structural characterization by MS and 1 H NMR spectroscopy confirmed the bridged porphyrin dimer structure. The properties of the dimers were characterized by IR, UV-visible absorption, fluorescence and magnetic circular dichroism (MCD) spectroscopy, and electrochemistry studies. Theoretical calculations were carried out to analyze the electronic structures of porphyrin dimers with a bridging amide-bonded xanthene moiety.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424615500492

Reference9 articles.

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