A novel hybrid blend based on phenoxy-substituted boron subphthalocyanine for organic photodetectors

Author:

Maklakov Sergey S.1,Dubinina Tatiana V.23,Osipova Marina M.2,Petrusevich Elizaveta F.2,Mishin Alexey D.1,Tomilova Larisa G.23

Affiliation:

1. Institute for Theoretical and Applied Electromagnetics of the Russian Academy of Sciences (ITAE RAS), Izhorskaya st., 13, Moscow, 125412, Russia

2. M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1, 119991, Moscow, Russia

3. Institute of Physiologically Active Compounds of the Russian Academy of Sciences (IPAC RAS), Severny proezd 1, 142432, Chernogolovka, Moscow Region, Russia

Abstract

Phenoxy-substituted boron subphthalocyanine, blended with a conductive polymer MEH-PPV, is presented as a photoresistive organic material. Using an easily accessible drop casting technique, the blend produces a thin-layer organic photoresistor with a photoresistive ratio of ~2–12. Variations in the blend composition and morphology are shown to change the transport properties of the material. The photoelectrochemical characteristics of the photoresistor are discussed in terms of impedance spectroscopy and the morphology of the material is analyzed using confocal fluorescent microscopy. The device developed is a daylight detector.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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