Intramolecular photoinduced electron transfer reactions of zinc(II) porphyrin dyads studied with a sub-ns time resolution

Author:

Sakakibara Kei1,Tomida Kenta1,Nakagawa Tatsuo2,Yagyu Takeyoshi3,Takagi Hideo D.4,Inamo Masahiko1

Affiliation:

1. Department of Chemistry, Aichi University of Education, Igaya, Kariya 448-8542, Japan

2. Unisoku Co. Ltd., 2-4-3 Kasugano, Hirakata 573-0131, Japan

3. Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Showa, Nagoya 466-8555, Japan

4. Research Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan

Abstract

We report the dynamics of a intramolecular photoinduced electron transfer reaction of Zn(II)-porphyrin dyads that have a 2,2[Formula: see text]-bipyridine moiety at the periphery in the presence of Cu[Formula: see text] in methanol studied using laser flash photolysis with a sub-nanosecond time resolution. The photoinduced electron transfer reactions were observed from the excited [Formula: see text] and [Formula: see text] states of the Zn(II)-porphyrin to the Cu(II)-2,2[Formula: see text]-bipyridine moiety, and the structural dependence of the reactivity were discussed in terms of the distance between the electron donating and accepting centers.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3