The solvation dynamics and rotational relaxation of protonated meso-tetrakis(4-sulfonatophenyl)porphyrin in imidazolium-based ionic liquids measured with a streak camera

Abstract

For the steady-state behavior of diprotonated tetrakis(4-sulfonatophenyl)porphyrin (H4TPPS2-) in five imidazolium ionic liquids (ILs), the absorption positions of H4TPPS2- primarily depend on the constituent ions of the ILs whereas the emission positions of H4TPPS2- strongly depend on the polarity of the ILs. The fluorescence spectra of H4TPPS2- with different excitation wavelengths show no red-edge effect in our system. The dynamics of H4TPPS2- in ILs is further studied with a streak camera, and the relaxation process of ILs occurs on two different time scales. The short lived component attributed to the local motion of the cations and the anions around the porphine core varies from 32 to 196 ps. The long lived one originated from the collective diffusive motions of the cations and anions varies from 460 to 1072 ps. The average solvation time depends on the viscosity of the ILs. The rotational relaxation times of H4TPPS2- decrease as the viscosity of the ILs decreases.