Synthesis of 10,20-substituted tetrabenzo-5,15-diazaporphyrin copper complexes from soluble precursors-Reference-Cited by-同舟云学术

Synthesis of 10,20-substituted tetrabenzo-5,15-diazaporphyrin copper complexes from soluble precursors

Published:2021-09-30 Issue:10n12 Volume:25 Page:1186-1192
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Sugano Yuki¹,Matsuo Kyohei¹,Hayashi Hironobu¹,Aratani Naoki¹,Yamada Hiroko¹

Affiliation:

1. Division of Materials Science, Graduate School of Science and Technology, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara 630-0192, Japan

Abstract

We report improved synthesis of the bicyclo[2.2.2]octadiene(BCOD)-fused 5,15-diazaporphyrin and meso-substituted derivatives by metal-template aza-annulation reaction. The obtained compounds act as the soluble precursors of tetrabenzo-5,15-diazaporphyrin (TBDAP) by thermal conversion. The substituents at meso-positions make significant differences in the optical properties and morphology in the thin film upon thermal conversion.

Funder

(JSPS) KAKENHI

Publisher

World Scientific Pub Co Pte Ltd

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424621501194

Reference26 articles.

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5. Effect of alkyl substituents: 5,15-bis(trimethylsilylethynyl)- vs. 5,15-bis(triisopropylsilylethynyl)-tetrabenzoporphyrins and their metal complexes

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1. Synthesis of bicyclo[2.2.2]octadiene-fused 5,15-diazaporphyrin and 10-azacorrole with meso-imine bridges;Journal of Porphyrins and Phthalocyanines;2023-02-13

2. Recent advances in the synthesis of diazaporphyrins and their chalcogen derivatives;Organic & Biomolecular Chemistry;2023

3. Synthesis and properties of 10,20-bis(triisopropylsilylethynyl)-tetrabenzo-5,15-diazaporphine;Journal of Porphyrins and Phthalocyanines;2022-12-28