Synthesis and characterization of highly soluble hexadecachloro- and hexadecafluorophthalocyanine ruthenium(II) complexes-Reference-Cited by-同舟云学术

Synthesis and characterization of highly soluble hexadecachloro- and hexadecafluorophthalocyanine ruthenium(II) complexes

Published:2005-09 Issue:09 Volume:09 Page:626-636
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Christendat Dharamdat¹,David Mary-Ann¹,Morin Sylvie¹,Lever A. B. P.¹,Kadish Karl M.²,Shao Jianguo²

Affiliation:

1. Department of Chemistry, York University, Toronto, Ontario M3J 1P3, Canada

2. Department of Chemistry, University of Houston, Houston, Texas 77204-5003, USA

Abstract

A new synthesis is reported for hexadecafluorophthalocyanineruthenium(II), F16Pc (2-) RuIIand hexadecachlorophthalocyanineruthenium(II), Cl16Pc (2-) RuII, is reported for the first time. These paramagnetic species, which contain no axial ligand, are quite reasonably soluble in a range of common organic solvents. We report and discuss electronic and vibrational (infrared and resonance Raman) spectroscopic, MALDI-TOF and magnetic data. In addition we report electrochemical data and use spectroelectrochemical methods to obtain the electronic spectra of these species in the phthalocyanine(1-), (3-) and (4-) oxidation states.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424605000733

Reference103 articles.

1. Industrial applications of phthalocyanines

2. Steamrollers, Sports Cars and Security: Phthalocyanine Progress Through the Ages

3. Phthalocyanines as materials for advanced technologies: some examples

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