5,10,15-Triarylcorrole atropisomerism-Reference-Cited by-同舟云学术

5,10,15-Triarylcorrole atropisomerism

Published:2020-01 Issue:01n03 Volume:24 Page:153-160
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Bischetti Martina¹,Pomarico Giuseppe¹,Nardis Sara¹,Mandoj Federica¹,Cicero Daniel O.¹,Paolesse Roberto¹

Affiliation:

1. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via Della Ricerca Scientifica, 1, 00133 Rome, Italy

Abstract

A series of 5,10,15-triarylcorroles has been prepared, with the meso-aryl rings functionalized with different substituents to investigate their influence on the aryl ring rotation with respect to the corrole plane. The study has been carried out by different NMR techniques, allowing the complete assignment of the 1H NMR spectra and giving insights on the kinetic and thermodynamic factors driving the atropisomerism in triarylcorrole derivatives.

Funder

University of Tor Vergata

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424619500706

Reference22 articles.

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