Affiliation:
1. School of Science, China University of Petroleum (East China), Qingdao 266580, China
2. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Abstract
An efficient enzymatic-free electrochemical sensor is firstly developed based on the self-assemblied film of a sandwich mixed (phthalocyaninato) (porphyrinato) europium(III) double-decker complex, Eu(Pc)[T(OH)PP], [Pc = phthalocyaninate, T(OH)PP = 5,10,15,tris (4-tert-butylphenyl)-20-(4-hydroxyphenyl)porphyrinate] prepared by using a solution-processing QLS method. The Eu(Pc)[T(OH)PP]semiconducting active layer on an ITO working electrode leads to a good sensing property for the detection of dopamine with an excellent selectivity, due to the high Eu(Pc)[T(OH)PP] molecular ordering/packing in the QLS film and more favorable interaction between the Eu(Pc)[T(OH)PP] and DA molecules. The amperometric responses are linearly proportional to the concentration of dopamine in the range of 8–100 [Formula: see text]M, with a low detection limit of 4.8 [Formula: see text]M and good sensitivity, indicating the great potential of electroactive tetrapyrrole rare earth sandwich type complexes in the field of nonenzymatic electrochemical sensors.
Publisher
World Scientific Pub Co Pte Lt
Cited by
13 articles.
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