meso-Carbazole substituted palladium porphyrins: Efficient catalysts for visible light induced oxidation of aldehydes-Reference-Cited by-同舟云学术

meso-Carbazole substituted palladium porphyrins: Efficient catalysts for visible light induced oxidation of aldehydes

Published:2021-04-23 Issue:05n06 Volume:25 Page:571-581
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Janaagal Anu¹,Pandey Vijayalakshmi¹,Sabharwal Sudhir¹,Gupta Iti¹

Affiliation:

1. Indian Institute of Technology Gandhinagar, Palaj Campus, Gandhinagar, Gujarat-382355, India

Abstract

The A3B and A2B2 type porphyrins having [Formula: see text]-butylcarbazole and [Formula: see text]-cyanophenyl groups are synthesized and characterized. Their palladium complexes have also been prepared and utilized as catalysts for the photo-oxidation reactions of aromatic aldehydes in good yields. Pd(II)porphyrins displayed decent phosphorescence at [Formula: see text]670 nm and were able to generate singlet oxygen upon light irradiation. The calculated singlet oxygen quantum yields for Pd(II)porphyrins were between 57% and 73%. The photo-catalytic application of Pd(II)porphyrins for aerobic oxidation of aromatic aldehydes is demonstrated.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424621500486

Reference43 articles.

1. 15 Combinatorial Libraries of Porphyrins: Chemistry and Applications

2. Heteroatom-Containing Porphyrin Analogues

3. The role of porphyrin chemistry in tumor imaging and photodynamic therapy

4. Synthetic aspects of carbazole containing porphyrins and porphyrinoids

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis of novel zinc porphyrins with bioisosteric replacement of Sorafenib: Efficient theranostic agents for anti-cancer application;Journal of Inorganic Biochemistry;2023-12

2. Robust Zinc(II)porphyrin Catalyst for Visible Light Induced C–H Arylation of Heteroarenes;The Journal of Organic Chemistry;2023-06-12

3. Meso-functionalized BODIPYs: Synthesis, molecular docking and photodynamic efficiency on breast cancer cells;Journal of Porphyrins and Phthalocyanines;2023-02-17

4. A2B2 type porphyrins with meso-donor groups: Synthesis, X-ray structures, DFT studies and photocatalytic application using sunlight;Dyes and Pigments;2023-01

5. NIR-Active Porphyrin-Decorated Lipid Microbubbles for Enhanced Therapeutic Activity Enabled by Photodynamic Effect and Ultrasound in 3D Tumor Models of Breast Cancer Cell Line and Zebrafish Larvae;ACS Applied Bio Materials;2022-08-12