The first push-pull μ-nitrido iron phthalocyanine dimer-Reference-Cited by-同舟云学术

The first push-pull μ-nitrido iron phthalocyanine dimer

Published:2013-09-09 Issue:10 Volume:17 Page:1022-1026
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

İşci Ümit¹

Affiliation:

1. Gebze Institute of Technology, Department of Chemistry, P.O. Box 141, Gebze 41400, Turkey

Abstract

The first push-pull μ-nitrido diiron phthalocyanine complex was prepared and characterized. The EPR spectrum confirms the Fe +3.5– N – Fe +3.5 formalism. The stability of this dimer in oxidant media (up to 1000 equivalent of H 2 O 2) was studied by UV-vis spectroscopy. The push-pull μ-nitrido diiron phthalocyanine exhibited excellent stability because of the delocalization of an unpaired electron.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424613500880

Reference5 articles.

1. Single-Atom Bridged Dinuclear Metal Complexes with Emphasis on Phthalocyanine Systems

2. Solvent-dependent rotational phenomena in μ-nitrido-[2,3,9,10,16,17,23,24-octa(n-pentoxy)phthalocyaninato]diiron complex

3. First Water-Soluble μ-Nitrido Dimer of Iron Phthalocyanine

4. Synthesis and properties of substituted (phthalocyaninato)-iron and -cobalt compounds and their pyridine adducts

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