Electrochemical approach to trifluoroacetamide synthesis from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) catalyzed by B12 complex-Reference-Cited by-同舟云学术

Electrochemical approach to trifluoroacetamide synthesis from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) catalyzed by B12 complex

Published:2021-02-25 Issue: Volume: Page:A-H
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Moniruzzaman Mohammad¹,Yano Yoshio¹,Ono Toshikazu¹,Hisaeda Yoshio¹,Shimakoshi Hisashi¹

Affiliation:

1. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Nishi-ku, 744, Fukuoka 819-0395, Japan

Abstract

One-pot synthetic approach to produce trifluoroacetamide has been developed using an electrochemical method with the B[Formula: see text] complex as a catalyst under mild conditions, in open air at room temperature. Thirty examples of trifluoroacetamide were synthesized from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) in moderate to good yields. This user-friendly strategy is compatible with a broad range of trifluoroacetamide syntheses.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424621500292

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