Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes-Reference-Cited by-同舟云学术

Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes

Published:2016-08 Issue:08n11 Volume:20 Page:1075-1081
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Furuyama Taniyuki¹²,Sugiyab Yusuke²,Yoshidab Takuya²,Kobayashi Nagao²³

Affiliation:

1. Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

2. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

3. Faculty of Textile Science and Technology, Shinshu University, Tokida, Ueda 386-8567, Japan

Abstract

Octa-(meta-methoxyphenyl) substituted tetraazaporphyrin (TAP, 1) and corrolazine (Cor, 4) phosphorus(V) complexes have been synthesized and characterized. 1 has a blue-shifted, small charge transfer (CT) band while para-methoxyphenyl substituted PTAP 2 has a red-shifted, intense CT band. The difference could be interpreted as an inductive effect of the meta-methoxy groups. The position and intensity of the absorption bands of 1 are well matched to the trend of para-substituted PTAPs. The synthesis of PCor from free-base TAP was also investigated. The PCor was not generated directly but from a PTAP intermediate

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424616500619

Reference10 articles.

1. Handbook of Porphyrin Science (Volume 1)

2. Phosphorus(v) tetraazaporphyrins: porphyrinoids showing an exceptionally strong CT band between the Soret and Q bands

3. Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

4. Synthesis and optical properties of tetraazaporphyrin phosphorus(V) complexes with electron-rich heteroatoms

5. Modulating the electronic properties of porphyrinoids: a voyage from the violet to the infrared regions of the electromagnetic spectrum

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