A new water-soluble sulfonated cobalt(II) phthalocyanines: Synthesis, spectral, coordination and catalytic properties-Reference-Cited by-同舟云学术

A new water-soluble sulfonated cobalt(II) phthalocyanines: Synthesis, spectral, coordination and catalytic properties

Published:2015-08 Issue:08 Volume:19 Page:983-996
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Vashurin Artur¹,Filippova Anna²,Znoyko Serafima³,Voronina Alena²,Lefedova Olga⁴,Kuzmin Ilya⁵,Maizlish Vladimir³,Koifman Oscar⁵

Affiliation:

1. Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

2. Faculty of Fundamental and Applied Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

3. Department of Technology of Fine Organic Synthesis, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

4. Department of Physical and Colloid Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

5. Research Institute of Macroheterocycles of Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

Abstract

Novel complexes of cobalt(II) with sulfonated derivatives of phthalocyanines are synthesized. The influence of the sulfonated group's number in peripheral substituent on solubility of macrocycle and ability to form ordered structures in solution is showed. Transition from H-aggregates to monomeric phthalocyanine structures and sandwich-type dimers was found during formation of metallophthalocyanine complexes with 1,4-diazabicyclo[2.2.2]octane. The catalytic activity of metallophthalocyanines was studied on the model of Merox process.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424615500753

Reference41 articles.

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2. Self-Assembly, Self-Organization: Nanotechnology and Vitalism

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