Heterogenization of manganese porphyrin via hydrogen bond in zeolite imidazolate framework-8 matrix, a host–guest interaction, as catalytic system for olefin epoxidation

Abstract

A heterogenized meso-tetrakis(2,3-dihydroxyphenyl)porphyrinatomanganese(III) acetate at zeolite imidazolate framework-8 (T(2,3-OHP)PorMn@ZIF-8) is investigated for the catalytic olefin epoxidation reactions at room temperature. Heterogenization is accomplished through a non-classical hydrogen bond proposed between T(2,3-OHP)PorMn bearing O–H groups and C–H of the 2-methylimidazolate linkers in the ZIF-8 structure. The aforementioned compound is characterized by X-ray powder diffraction (XRD), atomic absorption spectroscopy (AAS), nitrogen adsorption−desorption, FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The catalytic system with rather high potential of reusability is proposed as a fairly efficient epoxidation catalyst compared to reports in homogeneous media.