CALCULATION OF THE TRANSPORT PROPERTIES OF GASEOUS MIXTURES OF CF4 WITH O2, N2, CH4 AND CO2 AT LOW DENSITY USING SEMI-EMPIRICAL INVERSION METHOD

Author:

HAGHIGHI BEHZAD1,DJAVANMARDI ALIREZA HASSANI1,PAPARI MOHAMMAD MEHDI2

Affiliation:

1. Thermodynamic and Transport Properties Research Laboratory (T&TPRL), Chemistry Department, University of Birjand, P.O. Box 97175-615, Birjand, Southern Khorasan Province, Iran

2. Chemistry Department, Shiraz University of Technology, Shiraz 71555-313, Iran

Abstract

Viscosity and diffusion coefficients for four equimolar binary gaseous mixtures of CF 4 with O 2, N 2, CH 4 and CO 2 are determined from the extended principle of corresponding states by the inversion technique. The Lennard–Jones 12-6 (LJ 12-6) potential energy function is used as the initial model potential required by the technique. The interaction potential energies from the inversion procedure reproduce viscosity within 1% and diffusion coefficients within 5%.

Publisher

World Scientific Pub Co Pte Lt

Subject

Computational Mathematics,Computer Science (miscellaneous)

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