Effect of Y doping at Co site on thermoelectric properties of Ca3Co4O9

Abstract

In this work, our effort was to improve the thermoelectric properties of Ca3Co4O9 thermoelectric material. Ca3Co[Formula: see text]YxO9 polycrystalline thermoelectric ceramics have been fabricated by sol–gel method plus spontaneous combustion and cold isostatic pressing process. The structure, surface topography and thermoelectric properties of Ca3Co[Formula: see text]YxO9 polycrystalline thermoelectric were investigated by X-ray diffraction (XRD), SEM and ZEM3, respectively. The results showed that [Formula: see text] doping affected the microstructure and thermoelectric performance remarkable. With the increasing of [Formula: see text] doping, the electrical conductivity had a maximum value, and thermal conductivity has a minimum value. Seebeck coefficient gradually increased with [Formula: see text] doping content increasing always. The figure of merit was 0.07 at 673[Formula: see text]K for the Ca3Co[Formula: see text]Y[Formula: see text]O9 sample. The results showed that the thermoelectric performance of Ca3Co4O9 could be improved 39% with the substitution of [Formula: see text] than the un-doped.