Strongly Fluorescent Carbon Quantum Dots from Biomass Tar as Highly Selective and Sensitive Probe for Fe3+ Detection

Author:

Yuan Haoran1234,Zhang Xian1234,Li Denian123ORCID,Chen Yong123

Affiliation:

1. Laboratory for Integrated Technology of “Urban and Rural Mines” Exploitation, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, No. 2 Nengyuan Road, Wushan, Tianhe District, Guangzhou, Guangdong 510640, P. R. China

2. Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Beijing, P. R. China

3. Guangdong Provincial Key Laboratory of New and Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, P. R. China

4. University of Chinese Academy of Sciences, No. 19(A) Yuquan Road, Shijingshan District, Beijing 100049, P. R. China

Abstract

Nonhazardous and value-added utilization of biomass tar remains a great challenge in biomass gasification development. Herein, both model compounds and real biomass tar were for the first time tested as the carbon source for carbon quantum dots, where the resultants demonstrated excellent monodispersibility and strong fluorescence, quantum efficiency up to 53% and 43% were achieved. Moreover, the real tar-derived CQDs further revealed as a highly selective and sensitive probe for Fe[Formula: see text], indicating its great potential ion sensing. It is expected that this work would open up a new strategy for biomass tar valorization.

Funder

Natural Science Foundation of Guangdong Province

National Natural Science Foundation of China

Science and Technology Project of Guangdong Province

CAS Interdisciplinary Innovation Team

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,General Materials Science

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