Green Synthesis of Zinc Oxide Nanoparticles Derived from Solanum Nigrum Leaf Extract: An Analysis of the Structural, Optical, and Antibacterial Properties

Author:

Albert Helen Merina1ORCID,Kumar Nellore Manoj2ORCID,Asatkar Archana3ORCID,Sailaja J. Madhuri4ORCID,Mala N. Mani5ORCID,Raja Vaishnavi6ORCID,Bhatta Kalpita7ORCID

Affiliation:

1. Department of Physics, Sathyabama Institute of Science and Technology, Chennai, India

2. Department of Mathematics, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Chennai, India

3. Department of Chemistry, Government Nagarjuna P.G. College of Science, Raipur, Chhattisgarh, India

4. Department of Physics, BS & HSS, AUCEW, Andhra University, Visakhapatnam, Andhra Pradesh, India

5. Department of Botany, Government Degree College, Chintalapudi, Eluru, Andhra Pradesh, India

6. Department of Physics, Mother Teresa Women’s University, Attuvampatti, Kodaikanal, Tamil Nadu, India

7. Department of Botany, School of Applied Sciences, Centurion University of Technology and Management, Bhubaneswar, Odisha, India

Abstract

The “green synthesis” method is environmentally benign and cost-effective. This research study adopted an environmentally compatible method for creating Zinc oxide nanoparticles (ZnO NPs) using the capping element Solanum nigrum leaf extract. The X-ray diffraction, Fourier transforms infrared spectroscopy, energy dispersive X-ray analysis, UV-visible spectroscopy, fluorescence spectroscopy, field emission scanning electron microscopy, and antibacterial investigations were employed to evaluate the structural, spectroscopic, and antibacterial characterizations of the green synthesized ZnO NPs. It was shown that the generated ZnO NPs had a typical particle size of 27.75 nm and a wurtzite hexagonal form. FTIR spectroscopy has confirmed the presence of the functional groups in the generated sample. By using EDX analysis, the ZnO NPs’ fabrication and chemical composition have been determined. The surface texture and aggregation of nanostructure entities were examined using FESEM micrographs. Based on UV-Vis investigations, the bandgap of the ZnO NP was calculated to be 3.82 eV. The fluorescent spectra revealed a significant emission peak at 542 nm (green) for an excitation wavelength of 270 nm. The broad Stokes shift observed in fluorescent spectra is beneficial for practical purposes. The results of the antibacterial test shows that the as-synthesized ZnO NPs can be used in the healthcare and environmental sectors to prevent the growth of harmful bacteria.

Publisher

World Scientific Pub Co Pte Ltd

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